The
unanswered billion dollar question is how well do solar thermal storage technologies
rate on their metric?
The
Barnhart-Benson metric, Energy Stored On Invested (ESOI), is the ratio between
the energy a device can store in its entire life and the energy required to
build the device.
The
larger the ESOI, the better is the storage system. Larger values of ESOI can be obtained by
- increasing the number of cycles
- increasing the round-trip efficiency
- increasing the depth of discharge
- decreasing the embodied energy
|
Technology
|
ESOI
|
|
compressed
air energy storage
|
240
|
|
pumped
hydro storage
|
210
|
|
Li-ion
battery
|
10
|
|
Sodium-Sulphur
battery
|
6
|
|
Vanadium
redox battery
|
3
|
|
Zinc-Bromine
battery
|
3
|
|
Lead-acid
battery
|
2
|
The
conclusion by Barnhart & Benson was that
“over their
entire life, electrochemical storage technologies only store 2-10 times the
amount of energy that was required to build them”.
Clearly
that news will not be welcomed by proponents of electrochemical storage. You
can bet that feverish work is under way in hundreds of research laboratories
around the world to boost the ESOI score.
Published
information is available to evaluate the ESOI score for the most common solar
thermal storage technology – a molten 60-40 mixture of sodium and potassium
nitrates, commonly known as solar salt.
Burkhardt,
Heath and Turchi [2] made a life cycle assessment of a hypothetical 100 MW parabolic
trough concentrating solar plant at Daggett, California. The storage envisaged is 62,000 t of solar
salt, capable of storing 1,988 MWh of thermal energy, which can be converted
into an electrical equivalent by multiplying by the thermal-electric efficiency
of the plant.
Many
individual items were taken into account by Burkhardt et al. to calculate the
embodied energy of the storage component of the plant; these included obvious
items like steel, concrete, pumps, heat exchangers, insulation and solar
salt. However the biggest single item is
the energy required to keep the salt molten and stirred for daily operations.
It’s
noteworthy that the embodied energy of solar salt is low if it mined (as
assumed to be the case in [2]), but high if it produced synthetically. In the latter case, which Burkhardt et al.
say applies to slightly more than half of all installations, the manufacturing
process involves pre-production of ammonia, for which there is a natural gas
requirement.
I
have also made an as-yet unpublished estimate for the ESOI score for thermal
storage in air-blown pebble beds. This
estimate is in the context of a new concept for solar thermal power generation entitled BRRIMS,
denoting Brayton-cycle, Re-heated, Recuperated, Integrated, Modular and
Storage-equipped. Here what needs to be
considered is the embodied energy in hardware such as steel tanks, ducts,
concrete footings, insulation and pebbles.
Heat exchangers, pumps and fans are not required.
Results
of Barnhart & Benson can now be extended as follows, with the new data highlighted. This is a fair comparison (“apples with apples”)
between storage technologies since the new figures represent electrical energy
that would be produced from the underlying thermal storage.
|
Technology
|
ESOI
|
|
compressed
air energy storage
|
240
|
|
pumped
hydro storage
|
210
|
|
pebble bed thermal, BRRIMS
|
62
|
|
solar salt, parabolic trough [2]
|
47
|
|
Li-ion
battery
|
10
|
|
Sodium-Sulphur
battery
|
6
|
|
Vanadium
redox battery
|
3
|
|
Zinc-Bromine
battery
|
3
|
|
Lead-acid
battery
|
2
|
The
simple conclusion from the ESOI metric is that geologic storage is excellent,
thermal storage is good, whilst electrochemical storage is poor.
That
is not the whole story however.
Geological storage is not particularly cheap, and its applicability is
limited by the availability of suitable sites.
My estimates show that thermal storage is the cheapest option, and I propose
to present details of this work at the World
Renewable Energy Congress in July.
References
[1] C J Barnhart and S M Benson, “On the importance of reducing the energetic and material demands of electrical energy storage”, Energy Environ. Sci., 6 (2013), 1083.
[2] J J Burkhardt III, G A Heath and C S.
Turchi, “Life cycle assessment of a parabolic trough concentrating
solar power plant and the impacts of key design alternatives”, Environ. Sci.
Technol. 45
(2011), 2457–2464.
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